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bodies, and the medium which unites them, or, as the different atoms of a compound body may have different dispersive powers, while they exercise the same refractive force over a particular part of the spectrum, the rays for which this compensation takes place will be transmitted, while part of the complementary light is reflected.* Or in cases

where the refractive and dispersive powers are the same, the reflective forces of the particles may vary according to a different law, so that at the separating surfaces either white or coloured light may be reflected.†

In those cases of colour where the reflected and the transmitted tints are not complementary, as in leaf-gold, where the former is yellow and the latter green;-in leaf-silver, where they are white and blue, and in certain pieces of fir-wood, where the reflected light is whitish yellow, and the transmitted light a brilliant homogeneous red, we may explain the separation of the colours either by the principles we have already laid down or by the doctrine of thin plates. On the first principle, the colour of the reflected light, which is supposed to be the same as that of the transmitted light, will be modified by the law according to which the particles of the body attract different rays out of the beam of white light. In pitch, for example, the blue rays are first absorbed, so that at small thicknesses the transmitted light is a fine yellow, while, by the action of a greater thickness, the yellow itself is absorbed, and the transmitted light is a bright homogeneous red. Now in leaf-gold the transmitted colour of thinner films than we can obtain may be yellow, and, consequently, the light reflected from the first strata of interrupting faces will be yellow, and will determine the predominant tint of the reflected light. On the Newtonian doctrine, Mr. Herschel has explained it

* See the Phil. Trans. 1829, Part I. p. 189.

† Idem.

by saying, "that the transmitted rays have traversed the whole thickness of the medium, and therefore undergo many more times the action of its atoms than those reflected, especially those near the first surface to which the brighter part of the reflected colour is due."

The phenomena of the absorption of common and polarized light, which I have described in another place, throw much light on the subject of coloured bodies. The relation of the absorbent action to the axes of double refraction, and, consequently, to the poles of the molecules of the crystal, shows how the particles of light attracted by the molecules of the body will vary, both in their nature and number, according to the direction in which they approach the molecules; and explains how the colour of a body may be changed, either temporarily or permanently, by heat, according as it produces a temporary or a permanent change in the relative position of the molecules. This is not the place to enlarge on this subject; but we may be permitted to apply the idea to the curious experiment of Thenard on phosphorus. When this substance is rendered pure by repeated distillation, it is transparent, and transmits yellow light; but when it is thrown in a melted state into cold water, it becomes jet black. When again melted, it resumes its original colour and transparency. According to the Newtonian theory, we must suppose that the atoms of the phosphorus have been diminished in size by sudden cooling,-an effect which it is not easy to comprehend; but, according to the preceding views, we may suppose that the atoms of the phosphorus have been forced by sudden cooling into relative positions quite different from those which they take when they slowly assume the solid state, and their poles of maximum attraction, in

* Phil. Trans. 1819, p. 11.

place of being turned to one another, are turned in different directions, and then allowed to exercise their full action in attracting the intromitted light, and detaining it wholly within the body.*

Before concluding this chapter, there is one topic peculiarly deserving our notice, namely, the change of colour produced in bodies by continued exposure to light. The general effect of light is to diminish or dilute the colours of bodies, and in many cases to deprive them entirely of their colour. Now, it is not easy to understand how repeated undulations propagated through a body could diminish the size of its particles, or how the same effect could be produced by a multitude of reflections from particle to particle. But if light is attracted by the particles of bodies, and combines with them, it is easy to conceive that, when the molecules of a body have combined with a great number of particles of a green colour, for example, their power of combination with others will be diminished, and, consequently, the number of particles of any colour absorbed or detained must diminish with the time that the body has been exposed to light; that is, these particles must enter into the transmitted and reflected pencils, and diminish the intensity of their colour. If the body, for example, absorbs red light, and transmits and reflects green, then if the quantity of absorbed red light is diminished, it will enter into the reflected and transmitted pencils, and, forming white light by its mixture with a portion of the green rays, will actually dilute them in the same manner as if a portion of white light had been added.†

*If this view of the matter be just, we should expect that the specific gravity of the black would exceed that of the yellow phosphorus.

Since the two preceding chapters were written, I have had occasion to confirm and extend the views which they contain by many new experiments.

CHAPTER VIII.

Newton's Discoveries respecting the Inflection or Diffraction of Light -Previous Discoveries of Grimaldi and Dr. Hooke-Labours of succeeding Philosophers-Law of Interference of Dr. Young-Fresnel's Discoveries--New Theory of Inflection on the Hypothesis of the Materiality of Light.

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ALTHOUGH the discoveries of Newton respecting the Inflection of Light were first published in his Optics in 1704, yet there is reason to think that they were made at a much earlier period. Sir Isaac, indeed, informs us, in his preface to that great work, that the third book, which contains these discoveries, was put together out of scattered papers;" and he adds at the end of his observations, that "he designed to repeat most of them with more care and exactness, and to make some new ones for determining the manner how the rays of light are bent in their passage by bodies, for making the fringes of colours with the dark lines between them. But I was then interrupted, and cannot now think of taking these things into consideration." On the 18th March, 1674, Dr. Hooke had read a valuable memoir on the phenomena of diffraction; and, as Sir Isaac makes no allusion whatever to this work, it is the more probable that his "scattered papers" had been written previous to the communication of Dr. Hooke's experiments.

The phenomena of the inflection of light were first discovered by Francis Maria Grimaldi, a learned Jesuit, who has described them in a posthumous work published in 1665, two years after his death.* Having admitted a beam of the sun's light through

* Physico-Mathesis de Lumine coloribus et iride aliisque annexis. Bonon. 1665.

a small pin-hole in a piece of lead or card into a dark chamber, he found that the light diverged from this aperture in the form of a cone, and that the shadows of all bodies placed in this light were not only larger than might have been expected, but were surrounded with three coloured fringes, the nearest being the widest, and the most remote the narrowest. In strong light he discovered analogous fringes within the shadows of bodies, which increased in number with the breadth of the body, and became more distinct when the shadow was received obliquely and at a greater distance. When two small apertures or pin-holes were placed so near each other that the cones of light formed by each of them intersected one another, Grimaldi observed, that a spot common to the circumference of each, or, which is the same thing, illuminated by rays from each cone, was darker than the same spot when illuminated by either of the cones separately; and he announces this remarkable fact in the following paradoxical proposition, “that a body actually illuminated may become more dark by adding a light to that which it already receives."

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Without knowing what had been done by the Italian philosopher, our countryman, Dr. Robert Hooke, had been diligently occupied with the same subject. In 1672, he communicated his first observations to the Royal Society, and he then spoke of his paper as containing the discovery of a new property of light not mentioned by any optical writers before him." In his paper of 1674, already mentioned, and which is no doubt the one to which he alludes, he has not only described the leading phenomena of the inflection, or the deflection of light, as he calls it, but he has distinctly announced the doctrine of interference, which has performed so great a part in the subsequent history of optics.*

*This doctrine is thus announced. 1. That the same rays of light falling upon the same point of an object will turn into all sorts of colours

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